Homogeneous asymmetric catalysis offers reliable results and the possibility to 'tune' the catalysis on a rational basis. A pitfall, however, is that the separation of the catalyst from the starting material and products is difficult and often results in the loss of the catalytic material. Immobilization offers a potential solution for the user of enantioselective catalysts in industrial processes and laboratories. Heterogeneous catalysis allows continuous operations, recycling of the catalyst, and an easy separation of the reaction products, reducing both waste and costs. Chemists in academia and industry will welcome this careful selection of topics in this handbook that provides readers with practical and detailed information about the technical requirements for the immobilization of chiral catalysts, their application in synthesis, and methods for recycling.
This book distills the knowledge gained from research into atoms in molecules over the last 10 years into a unique, handy reference. Throughout, the authors address a wide audience, such that this volume may equally be used as a textbook without compromising its research-oriented character. Clearly structured, the text begins with advances in theory before moving on to theoretical studies of chemical bonding and reactivity. There follow separate sections on solid state and surfaces as well as experimental electron densities, before finishing with applications in biological sciences and drug-design. The result is a must-have for physicochemists, chemists, physicists, spectroscopists and materials scientists.
Serving as a general introduction to surface and interface science, this book focuses on basic concepts rather than specific details, and on intuitive understanding rather than merely learning facts. The text reflects the fact that the physics and chemistry of surfaces is a diverse area of research that involves classical scientific and engineering disciplines. As such, it discusses fundamental subjects, such as thermodynamics of interfaces, as well as applied topics including wetting, friction, and lubrication. Following an introduction to the most important techniques and methods, readers will be able to apply simple models to their own scientific problems. Furthermore, manifold high end technological applications are shown together with the basic scientific treatment, for example AFM, surface technology, biotechnology, microelectronics, and biomaterials. The book is written with advanced students of chemistry, physics, materials science, chemical engineering and related subjects who have a basic knowledge of natural sciences and mathematics in mind. In addition, scientists and engineers who are not yet specialists in surface science but want to learn more about this important subject will equally benefit.
From reviews of the previous volumes: 'This is an essential book for researchers in electrochemistry; it covers areas of both fundamental and practical importance, with reviews of high quality. The material is very well presented and the choice of topics reflects a balanced editorial policy that is welcomed.' The Analyst 'All the contributions in this volume are well up to the standard of this excellent series and will be of great value to electrochemists… The editors again deserve to be congratulated on this fine collection of reviews.' Journal of Electroanalytical Chemistry and Interfacial Chemistry '…competently and clearly written.' Berichte der Bunsen- Gesellschaft fur Physikalische Chemie
Surfactants are used throughout industry as components in a huge range of formulated products or as effect chemicals in the production or processing of other materials. A detailed understanding of the basis of their activity is required by all those who use surfactants, yet the new graduate or postgraduate chemist or chemical engineer will generally have little or no experience of how and why surfactants work. Chemistry & Technology of Surfactants is aimed at new graduate or postgraduate level chemists and chemical engineers at the beginning their industrial careers and those in later life who become involved with surfactants for the first time. The book is a straightforward and practical survey of the chemistry of surfactants and their uses, providing a basic introduction to surfactant theory, information on the various types of surfactant and some application details. This will allow readers to build onto their scientific education the concepts and principles on which the successful use of surfactants, across a wide range of industries, is based.
A new, definitive perspective of electrokinetic and colloid transport processes Responding to renewed interest in the subject of electrokinetics, Electrokinetic and Colloid Transport Phenomena is a timely overview of the latest research and applications in this field for both the beginner and the professional. An outgrowth of an earlier text (by coauthor Jacob Masliyah), this self-contained reference provides an up-to-date summary of the literature on electrokinetic and colloid transport phenomena as well as direct pedagogical insight into the development of the subject over the past several decades. A distinct departure from standard colloid science monographs, Electrokinetic and Colloid Transport Phenomena presents the most salient features of the theory in a simple and direct manner, allowing the book to serve as a stepping-stone for further learning and study. In addition, the book uniquely discusses numerical simulation of electrokinetic problems and demonstrates the use of commercial finite element software for solving these multiphysics problems. Among the topics covered are: * Mathematical preliminaries * Colloidal systems * Electrostatics and application of electrostatics * Electric double layer * Electroosmosis and streaming potential * Electrophoresis and sedimentation potential * London-Van der Waals forces and the DLVO theory * Coagulation and colloid deposition * Numerical simulation of electrokinetic phenomena * Applications of electrokinetic phenomena Because this thorough reference does not require advanced mathematical knowledge, it enables a graduate or a senior undergraduate student approaching the subject for the first time to easily interpret the theories. On the other hand, the application of relevant mathematical principles and the worked examples are extremely useful to established researchers and professionals involved in a wide range of areas, including electroosmosis, streaming potential, electrophoretic separations, industrial practices involving colloids and complex fluids, environmental remediation, suspensions, and microfluidic systems.
Covers important name reactions relevant to heterocyclic chemistry The field of heterocyclic chemistry has long presented a special challenge for chemists. Because of the enormous amount and variety of information, it is often a difficult topic to cover for undergraduate and graduate chemistry students, even in simplified form. Yet the chemistry of heterocyclic compounds and methods for their synthesis form the bedrock of modern medicinal chemical and pharmaceutical research. Thus there is a great need for high quality, up-to-date, and authoritative books on heterocyclic synthesis helpful to both the professional research chemist as well as the advanced student. Name Reactions in Heterocyclic Chemistry provides a one-stop repository for this important field of organic chemistry. The primary topics include three- and four-membered heterocycles, five-membered heterocycles including indoles, furans, thiophenes, and oxazoles, six-membered heterocycles including quinolines, isoquinolines, and pyrimidines, and other heterocycles. Each name reaction is summarized in seven sections: Description Historical perspective Mechanism Variations and improvements Synthetic utility Experimental References Authored by a team of world-renowned contributors – some of whom have discovered the very reactions they describe – Name Reactions in Heterocyclic Chemistry represents a state-of-the-art resource for students and researchers alike.
Compendium of Organic Synthetic Methods, Volume 11 continues the motivation of the series, which is to facilitate the search for quality, selected functional group transformations, organized by reacting functional group of starting material and functional group formed, with full references to each reaction.
Computational Chemistry Using the PC, Third Edition takes the reader from a basic mathematical foundation to beginning research-level calculations, avoiding expensive or elaborate software in favor of PC applications. Geared towards an advanced undergraduate or introductory graduate course, this Third Edition has revised and expanded coverage of molecular mechanics, molecular orbital theory, molecular quantum chemistry, and semi-empirical and ab initio molecular orbital approaches. With significant changes made to adjust for improved technology and increased computer literacy, Computational Chemistry Using the PC, Third Edition gives its readers the tools they need to translate theoretical principles into real computational problems, then proceed to a computed solution. Students of computational chemistry, as well as professionals interested in updating their skills in this fast-moving field, will find this book to be an invaluable resource.
Organic transformations are the heart of synthetic organic chemistry. The Compendium of Organic Synthetic Methods series facilitates the search for the most useful functional group transformations in organic chemistry. Compendium of Organic Synthetic Methods, Volume 9, provides quick access to proven protocols for the newest, most useful reactions and transformations. It contains both functional group transformations and bond-forming reactions, and focuses on the use of reagents readily available or easily prepared and handled in the laboratory. This valuable desktop resource contains over 1,200 examples of published reactions for the preparation of monofunctional compounds in a handy reference, as well as over 800 examples of difunctional compounds, and features over 30 more reviews than Volume 8. As in all the previous Compendium volumes, the classification schemes used allow for quick and easy reference and information retrieval. Chemical transformations are classified by the reacting functional group of the starting material and then by the functional group formed. Helpful indices are provided for both monofunctional and difunctional compounds as an efficient means of guidance to specific classes of transformations. Compendium of Organic Synthetic Methods, Volume 9, is an unparalleled source of information on the methods, reactions, and transformations in contemporary organic chemistry for the working chemist and student. Volume 9 in the series originated by I. T. Harrison and S. Harrison