John Wiley & Sons Limited
Все книги издательства John Wiley & Sons LimitedModels for Bonding in Chemistry
A readable little book assisting the student in understanding, in a nonmathematical way, the essentials of the different bonds occurring in chemistry. Starting with a short, self-contained,introduction, Chapter 1 presents the essential elements of the variation approach to either total or second-order molecular energies, the system of atomic units (au) necessary to simplify all mathematical expressions, and an introductory description of the electron distribution in molecules. Using mostly 2x2 Hückel secular equations, Chapter 2, by far the largest part of the book because of the many implications of the chemical bond, introduces a model of bonding in homonuclear and heteronuclear diatomics, multiple and delocalized bonds in hydrocarbons, and the stereochemistry of chemical bonds in polyatomic molecules, in a word, a model of the strong first-order interactions originating the chemical bond. In Chapter 3 the Hückel model of the linear polyene chain is used to explain the origin of band structure in the 1-dimensional crystal. Chapter 4 deals with a simple two-state model of weak interactions, introducing the reader to understand second-order electric properties of molecules and VdW bonding between closed shells. Lastly, Chapter 5 studies the structure of H-bonded dimers and the nature of the hydrogen bond, which has a strength intermediate between a VdW bond and a weak chemical bond. Besides a qualitative MO approach based on HOMO-LUMO charge transfer from an electron donor to an electron acceptor molecule, a quantitative electrostatic approach is presented yielding an electrostatic model working even at its simplest pictorial level. A list of alphabetically ordered references, author and subject indices complete the book.
The Chemistry and Biology of Volatiles
Coming to a conclusion, this wonderful, informative and very interesting book presents an excellent overview of small volatile organic compounds and their role in our life and environment. Really fascinating is the entirety of scientific disciplines which were addressed by this book. –Flavour and Fragrance Journal, 2011 «… this book deserves to be a well-used reference in the library of any laboratory specialising in VOC». –Chemistry World, 2011 Volatile compounds are molecules with a relatively low molecular weight allowing for an efficient evaporation into the air. They are found in many areas of our everyday-life: they are responsible for the communication between species such as plants, insects or mammals; they serve as flavours or fragrances in many food products or perfumed consumer articles; and they play an important role in atmospheric chemistry. This book takes an interdisciplinary approach to volatile molecules. Review-style introductions to the main topics in volatile chemistry and biology are provided by international experts, building into a broad overview of this fascinating field. Topics covered include: The structural variety of volatile compounds Biogeneration of volatiles Synthesis of natural and non-natural volatiles Analysis of volatiles Volatile compounds as semiochemicals in plant-plant or plant-insect interactions Volatiles in pest control Pheromones and the influence of volatiles on mammals Olfaction and human perception Volatiles as fragrances The generation of flavours and food aroma compounds Stabilisation and controlled release of volatiles The impact of volatiles on the environment and the atmosphere
Solid Waste Technology and Management
The collection, transportation and subsequent processing of waste materials is a vast field of study which incorporates technical, social, legal, economic, environmental and regulatory issues. Common waste management practices include landfilling, biological treatment, incineration, and recycling – all boasting advantages and disadvantages. Waste management has changed significantly over the past ten years, with an increased focus on integrated waste management and life-cycle assessment (LCA), with the aim of reducing the reliance on landfill with its obvious environmental concerns in favour of greener solutions. With contributions from more than seventy internationally known experts presented in two volumes and backed by the International Waste Working Group and the International Solid Waste Association, detailed chapters cover: Waste Generation and Characterization Life Cycle Assessment of Waste Management Systems Waste Minimization Material Recycling Waste Collection Mechanical Treatment and Separation Thermal Treatment Biological Treatment Landfilling Special and Hazardous Waste Solid Waste Technology & Management is a balanced and detailed account of all aspects of municipal solid waste management, treatment and disposal, covering both engineering and management aspects with an overarching emphasis on the life-cycle approach.
An Introduction to Advanced Quantum Physics
An Introduction to Advanced Quantum Physics presents important concepts from classical mechanics, electricity and magnetism, statistical physics, and quantum physics brought together to discuss the interaction of radiation and matter, selection rules, symmetries and conservation laws, scattering, relativistic quantum mechanics, apparent paradoxes, elementary quantum field theory, electromagnetic and weak interactions, and much more. This book consists of two parts: Part 1 comprises the material suitable for a second course in quantum physics and covers: Electromagnetic Radiation and Matter Scattering Symmetries and Conservation Laws Relativistic Quantum Physics Special Topics Part 2 presents elementary quantum field theory and discusses: Second Quantization of Spin 1/2 and Spin 1 Fields Covariant Perturbation Theory and Applications Quantum Electrodynamics Each chapter concludes with problems to challenge the students’ understanding of the material. This text is intended for graduate and ambitious undergraduate students in physics, material sciences, and related disciplines.
Data Analysis in Vegetation Ecology
Evolving from years of teaching experience by one of the top experts in vegetation ecology, Data Analysis in Vegetation Ecology aims to explain the background and basics of mathematical (mainly multivariate) analysis of vegetation data. The book lays out the basic operations involved in the analysis, the underlying hypotheses, aims and points of views. It conveys the message that each step in the calculations has a specific, straightforward meaning and that patterns and processes known by ecologists often find their counterpart in mathematical operations and functions. The first chapters introduce the elementary concepts and operations and relate them to real-world phenomena and problems. Later chapters concentrate on combinations of methods to reveal surprising features in data sets. Showing how to find patterns in time series, how to generate simple dynamic models, how to reveal spatial patterns and related occurrence probability maps.
The Chemical Biology of Nucleic Acids
With extensive coverage of synthesis techniques and applications, this text describes chemical biology techniques which have gained significant impetus during the last five years. It focuses on the methods for obtaining modified and native nucleic acids, and their biological applications. Topics covered include: chemical synthesis of modified RNA expansion of the genetic alphabet in nucleic acids by creating new base pairs chemical biology of DNA replication: probing DNA polymerase selectivity mechanisms with modified nucleotides nucleic-acid-templated chemistry chemical biology of peptide nucleic acids (PNA) the interactions of small molecules with DNA and RNA the architectural modules of folded RNAs genesis and biological applications of locked nucleic acid (LNA) small non-coding RNA in bacteria microRNA-guided gene silencing nucleic acids based therapies innate immune recognition of nucleic acid light-responsive nucleic acids for the spatiotemporal control of biological processes DNA methylation frameworks for programming RNA devices RNA as a catalyst: The Diels-Alderase-Ribozyme evolving an understanding of RNA function by in vitro approaches the chemical biology of aptamers: synthesis and applications nucleic acids as detection tools bacterial riboswitch discovery and analysis The Chemical Biology of Nucleic Acids is an essential compendium of the synthesis of nucleic acids and their biological applications for bioorganic chemists, chemical biologists, medicinal chemists, cell biologists, and molecular biologists.
Cardiotoxicity of Non-Cardiovascular Drugs
Some drugs which are not aimed at treating heart disease have nevertheless been found to have profound effects on heart muscle. Cardiotoxicity is one of the major forms of toxicity seen in drugs and it accounts for most drug recalls and delays experienced in regulatory approvals.In recent years a number of non-cardiac blockbuster drugs such as terfenadine have been withdrawn from major markets because of cardiotoxicity concerns, while other drugs have either been withdrawn prior to marketing or required labelling changes that significantly restricted their use. In Cardiotoxicity of Non-Cardiovascular Drugs international experts describe the molecular mechanisms and clinical read-outs of cardiac events induced by a broad variety of noncardiovascular drugs. Particular emphasis is paid to the preclinical screening of drug cardiotoxicity. Topics include: metabolic targets of cardiotoxicity regulatory aspects translating molecular mechanisms into clinical trials structure-activity relationships in arrhythmias by antihistamines and psychoactive drugs cardiovascular toxicity of antitumor drugs cardiovascular toxicities of non-steroidal anti-inflammatory drugs cardiovascular toxicities of antiretroviral therapies Cardiotoxicity of Non-Cardiovascular Drugs is an essential guide to this important area of drug development. It will find a place on the bookshelves of researchers, regulators and students in medicinal chemistry, drug development, pharmacology, pharmacy and cardiovascular disease.
Analysis of Financial Time Series
This book provides a broad, mature, and systematic introduction to current financial econometric models and their applications to modeling and prediction of financial time series data. It utilizes real-world examples and real financial data throughout the book to apply the models and methods described. The author begins with basic characteristics of financial time series data before covering three main topics: Analysis and application of univariate financial time series The return series of multiple assets Bayesian inference in finance methods Key features of the new edition include additional coverage of modern day topics such as arbitrage, pair trading, realized volatility, and credit risk modeling; a smooth transition from S-Plus to R; and expanded empirical financial data sets. The overall objective of the book is to provide some knowledge of financial time series, introduce some statistical tools useful for analyzing these series and gain experience in financial applications of various econometric methods.
Geotechnical Engineering in Residual Soils
Wiley has long held a pre-eminent position as a publisher of books on geotechnical engineering, with a particular strength in soil behavior and soil mechanics, at both the academic and professional level. This reference will be the first book focused entirely on the unique engineering properties of residual soil. Given the predominance of residual soils in the under-developed parts of the United States and the Southern Hemisphere, and the increasing rate of new construction in these regions, the understanding of residual soils is expected to increase in importance in the coming years. This book will be written for the practicing geotechnical engineer working to any degree with residual soils. It will describe the unique properties of residual soil and provide innovative design techniques for building on it safely.The author will draw on his 30 years of practical experience as a practicing geotechnical engineer, imbuing the work with real world examples and practice problems influenced by his work in South America and Southeast Asia.
Guidelines for Process Safety Acquisition Evaluation and Post Merger Integration
CCPS (Center for Chemical Process Safety)
It is crucial for process safety professionals to be aware of best practices for post merger integration at any level. A compilation of industry best practices from both technical and financial perspectives, this book provides a single reference that addresses acquisitions and merger integration issues related to process safety. Presently, there are limited references on how to handle acquisitions in several different CCPS publications and almost no coverage of the post-merger integration issue, so this reference fills a notable gap in the coverage.