Pollutants and Water Management. Группа авторов

State distribution of grossly polluting industries in India.

Table 3.1 Four major states comprising large numbers of grossly polluting industries as per the Central Pollution Control Board report 2019.

States	Total no. of industries	No. of operational industries	No. of complying industries	No. of noncomplying industries
Andhra Pradesh	198	193	189	4
Gujarat	191	178	139	39
Haryana	660	638	625	13
Uttar Pradesh	1218	1079	950	129
Total GPIs in India	2743	2497	2222	275

3.5 Different Type of Grossly Polluting Industries and their Impact on Water Bodies

      MoEFCC notified 17 categories of GPIs engaged in different production systems (https://cpcbenvis.nic.in/cpcb_newsletters/PollutingIndustries.pdf):

       Chlor alkali/copper smelting

       Integrated iron industry/dyes and intermediates

       Sugar

       Distilleries

       Fertilizers

       Cement plants

       Petrochemicals

       Pulp and paper

       Pesticides

       Tanneries

       Textile and dye industries

       Oil refineries

       Pharmaceutical

       Zinc smelting

       Copper smelting

       Aluminum smelting

       Thermal power plants

Most of these industries are situated near riverbanks where the untreated/partially treated wastewater is discharged directly into river bodies thereby deteriorating water quality (Paul 2017). Wastewater generated from industries results from the production process and the final effluent includes both residual wastewater and final treated effluent. The report of the Ministry of Water Resource (MoWR) concluded that around 62% of wastewater is generated from large and medium‐scale industries whereas small‐scale industries generate 32% of wastewater. Water consumption in the Indian industrial sector is 2–3.5 more per unit of production compared with similar plants operating in other countries (www.downtoearth.org.in/news/pollution/grossly‐polluting‐industries‐more‐than‐doubled‐in‐8‐years‐soe‐in‐figures‐64962). Some major industries and their discharged pollutants are discussed in the following sections.

      3.5.1 The Textile Industry

      In India, the textile industry ranks in second place for providing employment, with 45 million people, and according to estimates, it will increase to 55 million by 2020 (Invest India 2019a); 2.3% contribution was made by the textiles industry and 13% to industrial production of gross domestic product (GDP) contribution. During the manufacturing process, a huge quantity of water is utilized, while, at the same time, water effluent is generated that consists of dyes, heavy metals, organic and inorganic wastes, detergents, and surfactants. According to Manikandan et al. (2015), the quality of water released from textile units are turbid, loaded with high organic and inorganic constituents, and possess a low BOD/COD ratio, which means that a large proportion of the water is nonbiodegradable and is not fit for any application if discharged directly. According to the study carried out by Kumar et al. (2020), it was concluded that for an average production capacity of 8000 kg of fabric/day, the amount of freshwater utilized is around 1.6 million liters/day, which generates 200–350 m³ of wastewater/ton of finished products, thus introducing 100 kg COD/ton of fabric to the water body.

      3.5.2 The Leather Industry

      India's contribution to the leather industry is 12.9% of the world's total leather manufacture, which produces around 3 billion square feet of leather yearly and provides employment to more than 4 million individuals (Invest India 2019b). The major pollutants present in wastewater discharged from the tanneries are chromium, salts, solids, sulfides, alkalinity, lime, etc. The characteristics of tannery wastewater are high chromium (Cr) concentration (toxic element having an adverse effect on flora and fauna and to the human beings), high BOD and COD, high total dissolved solids (TDS), and high total suspended solids (TSS). Kanpur's leather tanning industries are among the major contributors to river pollution and are classified by the MoEFCC as “Red Category” industries in India (MoEFCC 2017). Untreated or potentially processed effluents have risen to 20 times the number of contaminants, such as cyanide and chromium, in 22 highly contaminated regions of the world. It increases the BOD from 10–190 times, which can destroy human life in the affected region in severe situations. The research conducted by Dandira and Madanhire in 2013 also reported that COD in wastewater discharged via tanneries is in the range of 1000–43000 mg/l, which is 25–275 times greater than normal COD (Chaudhary and Walker 2019).

      3.5.3 Food‐Related Industries

The growth rate of the food industry in India was 322 billion dollars in 2016 and is estimated to increase to 543 billion dollars in 2020. Different types of food processing industries are grain, beverage, dairy, and edible oil industries (Invest India 2020). Different wastes released from food‐processing industries are poultry, dairy, meat, sugar processing, etc. All these wastes are highly degradable and when they enter water bodies, they decrease the DO level to a significant extent. Major industrial discharges are organic contaminants rich in fats, proteins, and pathogens. The quality of effluents from food processing units have moderate to high BOD, high COD, TSS, and TDS, and large nutrient contents such as nitrogen, phosphorous, heavy grease, and oil.

      3.5.4 The Metal Industry

      The major processes involved in the metal industry are mining, ore refining, alloying, casting, and sheet/folding. The most widely used techniques for the manufacture of metals are open‐hearth furnaces, oxygen incinerators, blast furnaces, and electric arc boilers (MOI 2015). An excess amount of water is generated from metal processing; the water is highly acidic and rich in toxic elements, for example, cyanogens, phenols, coke, metal, soluble bases, limestone, oils, etc.

      3.5.5 The Paper and Pulp Industry

      Rice husk, wood, cellulose, fibers, and waste papers are the main materials used for paper production. The