Mathematics for Enzyme Reaction Kinetics and Reactor Performance. F. Xavier Malcata

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Название Mathematics for Enzyme Reaction Kinetics and Reactor Performance
Автор произведения F. Xavier Malcata
Жанр Химия
Серия
Издательство Химия
Год выпуска 0
isbn 9781119490333



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having relabeled θ1 and θ2 to y and x, respectively. Equation (2.321), known as the basic angle transformation formula, permits calculation of the cosine of a difference of angles based on knowledge of sine and cosine of the individual angles – and is actually valid, irrespective of the relative amplitude of angles θ1 and θ2. If θ2 is set equal to π/2 in particular, then Eq. (2.320) becomes

      (2.322)equation

      which reduces to

      After rewriting Eq. (2.321) as

      (2.324)equation

      at the expense of Eqs. (2.295) and (2.296), and changing notation of −y to y (in view of its being a dummy variable), one obtains

      Eq. (2.325) permits rapid calculation of the cosine of a sum of two arguments, again based on the sine and cosine of the individual arguments. On the other hand, Eqs. (2.294) and (2.323) allow reformulation of Eq. (2.321) to

      where the argument of the left‐hand side may be rearranged to read

      – so the difference between the two cross products of sine and cosine of arguments x and y allows generation of sine of the corresponding difference.

      In view of the definition of tangent conveyed by Eq. (2.299), one may write

      (2.331)equation

      (2.332)equation

      where insertion of Eq. (2.299) allows simplification to

      (2.334)equation

      where division of both numerator and denominator of the right‐hand side simultaneously by cos x and cos y unfolds

      On the other hand, one may take reciprocals of both sides of Eq. (2.333) to get

      (2.337)equation

      with division of both numerator and denominator of the right‐hand side by tan x and tan y yielding