Synthesis Gas. James G. Speight

common biomass-to-energy process. Different types of woody fuels can typically be mixed together as a common fuel, although differing moisture content and chemical makeup can affect the overall conversion rate or efficiency of a biomass project.

There are at least six subgroups of woody fuels: (i) forestry residues which include in-forest woody debris and slash from logging and forest management activities, (ii) mill residues which include byproducts such as sawdust, hog fuel, and wood chips from lumber mills, plywood manufacturing, and other wood processing facilities, (iii) agricultural residues which includes byproducts of agricultural activities including crop wastes, waste from vineyard and orchard pruning, and rejected agricultural products, (iv) urban wood and yard wastes which includes residential organics collected by municipal programs or recycling centers and construction wood wastes, (v) dedicated biomass crops which includes trees, corn, oilseed rape, and other crops grown as dedicated feedstocks for a biomass project, and (vi) chemical recovery fuels – sometimes known as black liquor) – which includes woody residues recovered out of the chemicals used to separate fiber for the pulp and paper industry. Mill residues are a much more economically attractive fuel than forestry residues, since the in-forest collection and chipping are already included as part of the commercial mill operations. Biomass facilities collocated with and integral to the mill operation have the advantage of eliminating transportation altogether and thus truly achieve a no-cost fuel.

      Softwood residues are generally in high demand as feedstocks for paper production, but hardwood timber residues have less demand and fewer competing uses. In the past, as much as 50% of the tree was left on site at the time of harvest. Whole tree harvest systems for pulp chips recover a much larger fraction of the wood. Wood harvests for timber production often generate residues which may be left on the site or recovered for pulp production. Economics of wood recovery depend greatly on accessibility and local demand. Underutilized wood species include Southern red oak, poplar, and various small-diameter hardwood species. Unharvested dead and diseased trees can comprise a major resource in some regions. When such timber has accumulated in abundance, it comprises a fire hazard and must be removed. Such low-grade wood generally has little value and is often removed by prescribed burns in order to reduce the risk of wildfires.

      Agricultural residues are basically biomass materials that are byproducts of agriculture. This includes materials such as cotton stalks, wheat and rice straw, coconut shells, maize and jowar cobs, jute sticks, and rice husks. Many developing countries have a wide variety of agricultural residues in ample quantities. Large quantities of agricultural plant residues are produced annually worldwide and are vastly underutilized. The most common agricultural residue is the rice husk, which makes up approximately 25% w/w of the rice.

      Corn stalks and wheat straws are the two agricultural residues produced in the largest quantities. However, many other residues such as potato and beet waste may be prevalent in some regions. In addition to quantity it is necessary to consider density and water content (which may restrict the feasibility of transportation) and seasonality which may restrict the ability of the conversion plant to operate on a year-round basis. Facilities designed to use seasonal crops will need adequate storage space and should also be flexible enough to accommodate alternative feedstocks such as wood residues or other wastes in order to operate year-around. Some agricultural residues need to be left in the field in order to increase tilth (the state of aggregation of soil and its condition for supporting plant growth and to reduce erosion) but some residues such as corncobs can be removed and converted without much difficultly.

Agricultural residues can provide a substantial amount of biomass fuel. Similar to the way mill residues provide a significant portion of the overall biomass consumption in areas that are copiously forested, agricultural residues from sugar cane harvesting and processing provide a significant portion of the total biomass consumption in other parts of the world. One significant issue with agricultural residues is the seasonal variation of the supply. Large residue volumes follow harvests, but residues throughout the rest of the year are minimal. Biomass facilities that depend significantly on agricultural residues must either be able to adjust output to follow the seasonal variation, or have the capacity to stockpile a significant amount of fuel.

      Dry animal manure, which is typically defined as having a moisture content less than 30% w/w, is produced by feedlots and livestock corrals, where the manure is collected and removed only once or twice a year. Manure that is scraped or flushed on a more frequent schedule can also be separated, stacked, and allowed to dry. Dry manure can be composted or can fuel a biomass-to-energy combustion project. Animal manure does have value to farmers as fertilizer, and a biomass-to-energy project would need to compete for the manure. However, the total volume of manure produced in many livestock operations exceeds the amount of fertilizer required for the farmlands and, in some areas/countries, nutrient management plans are beginning to limit the over-fertilization of farmlands. Therefore, although there are competitive uses for the manure and low-cost disposal options at this time, manure disposal is going to become more costly over time, and the demand for alternative disposal options, including biomass-to-energy, will only increase.

      Biomass technologies present attractive options for mitigating many of the environmental challenges of manure wastes. The most common biomass technologies for animal manures are combustion, anaerobic digestion, and composting. Moisture content of the manure and the amount of contaminants, such as bedding, determine which technology is most appropriate.

      Urban wastes include municipal solid waste that is generated by household and commercial activities and liquid waste or sewage. Most municipal solid waste is currently disposed of in landfill sites. However, the disposal of this waste is a growing problem worldwide. Much of the waste could be used for energy production though incineration and processes. Japan currently incinerates more than 80% of the available municipal solid waste. It is also possible to use the methane produced in landfill sites for energy production.

      Urban wood and yard wastes are similar in nature to agricultural residues in many regards. A biomass facility will rarely need to purchase urban wood and yard wastes, and most likely can charge a tipping fee to accept the fuel. Many landfills are already sorting waste material by isolating wood waste. This waste could be diverted to a biomass project, and although the volume currently accepted at the landfills would not be enough on its own to fuel a biomass project, it could be an important supplemental fuel and could provide more value to the community in which the landfill resides through a biomass project than it currently does as daily landfill cover.

      Municipal solid wastes are produced and collected each year with the vast majority being disposed of in open fields. The biomass resource in municipal solid waste comprises the putrescible materials, paper and plastic and averages 80% of the total municipal solid waste collected. Municipal solid waste can be converted into energy by direct combustion, or by natural anaerobic digestion in the engineered landfill. At the landfill sites the gas produced by the natural decomposition of municipal solid waste (approximately 50% methane and 50% carbon dioxide) is collected from the stored material and scrubbed and cleaned before feeding into internal combustion engines or gas turbines to generate heat and power. The organic fraction of municipal solid waste can be anaerobically stabilized in a high-rate digester to obtain biogas for electricity or steam generation.

1.4 Energy Supply

Energy supply (energy flow) is the delivery of fuels or transformed fuels to point of consumption and the term potentially encompasses the extraction, transmission, generation distribution, and storage of fuels. This supply of energy can be disrupted by several factors, including imposition of higher energy prices due to action by OPEC (in the case of crude oil) or other cartel, war, political disputes, economic disputes, or physical damage to the energy infrastructure due to terrorism. The security of energy supply is a major concern of national security and energy independence.

      1.4.1 Economic Factors

      Crude oil economics is, as might be expected if the peak oil theory is true, dominated by the so-called occurrence of the remaining reserves that are to be depleted in the very near future. While there may be varied volatility in the price of crude oil, when there is a belief that the price in the