From natural rubber to fully synthetic polymers like nylon and teflon and up to biodegradable yoghurt cups: Georg Schwedt shows the whole spectrum of plastics, their development and applications as well as their influence on our daily life.
Diazonium compounds are employed as a new class of coupling agents to link polymers, biomacromolecules, and other species (e. g. metallic nanoparticles) to the surface of materials. The resulting high performance materials show improved chemical and physical properties and find widespread applications. The advantage of aryl diazonium salts compared to other surface modifiers lies in their ease of preparation, rapid (electro)reduction, large choice of reactive functional groups, and strong aryl-surface covalent bonding. This unique book summarizes the current knowledge of the surface and interface chemistry of aryl diazonium salts. It covers fundamental aspects of diazonium chemistry together with theoretical calculations of surface-molecule bonding, analytical methods used for the characterization of aryl layers, as well as important applications in the field of electrochemistry, nanotechnology, biosensors, polymer coatings and materials science. Furthermore, information on other surface modifiers (amines, silanes, hydrazines, iodonium salts) is included. This collection of 14 self-contained chapters constitutes a valuable book for PhD students, academics and industrial researchers working on this hot topic.
The only standard reference in this exciting new field combines the physical, chemical and material science perspectives in a synergic way. This monograph traces the development of the preparative methods employed to create nanostructures, in addition to the experimental techniques used to characterize them, as well as some of the surprising physical effects. The chapters cover every category of material, from organic to coordination compounds, metals and composites, in zero, one, two and three dimensions. The book also reviews structural, chemical, optical, and other physical properties, finishing with a look at the future for chiral nanosystems.
This practical book in instrumental analytics conveys an overview of important methods of analysis and enables the reader to realistically learn the (principally technology-independent) working techniques the analytical chemist uses to develop methods and conduct validation. What is to be conveyed to the student is the fact that analysts in their capacity as problem-solvers perform services for certain groups of customers, i.e., the solution to the problem should in any case be processed in such a way as to be «fit for purpose». The book presents sixteen experiments in analytical chemistry laboratory courses. They consist of the classical curriculum used at universities and universities of applied sciences with chromatographic procedures, atom spectrometric methods, sensors and special methods (e.g. field flow fractionation , flow injection analysis and N-determination according to Kjeldahl). The carefully chosen combination of theoretical description of the methods of analysis and the detailed instructions given are what characterizes this book. The instructions to the experiments are so detailed that the measurements can, for the most part, be taken without the help of additional literature. The book is complemented with tips for effective literature and database research on the topics of organisation and the practical workflow of experiments in analytical laboratory, on the topic of the use of laboratory logs as well as on writing technical reports and grading them (Evaluation Guidelines for Laboratory Experiments). A small introduction to Quality Management, a brief glance at the history of analytical chemistry as well as a detailed appendix on the topic of safety in analytical laboratories and a short introduction to the new system of grading and marking chemicals using the «Globally Harmonized System of Classification and Labelling of Chemicals (GHS)», round off this book. This book is therefore an indispensable workbook for students, internship assistants and lecturers (in the area of chemistry, biotechnology, food technology and environmental technology) in the basic training programme of analytics at universities and universities of applied sciences.
A mathematically rigorous explanation of how manufacturing deviations and damage on the working surfaces of gear teeth cause transmission-error contributions to vibration excitations Some gear-tooth working-surface manufacturing deviations of significant amplitude cause negligible vibration excitation and noise, yet others of minuscule amplitude are a source of significant vibration excitation and noise. Presently available computer-numerically-controlled dedicated gear metrology equipment can measure such error patterns on a gear in a few hours in sufficient detail to enable accurate computation and diagnosis of the resultant transmission-error vibration excitation. How to efficiently measure such working-surface deviations, compute from these measurements the resultant transmission-error vibration excitation, and diagnose the manufacturing source of the deviations, is the subject of this book. Use of the technology in this book will allow quality spot checks to be made on gears being manufactured in a production run, to avoid undesirable vibration or noise excitation by the manufactured gears. Furthermore, those working in academia and industry needing a full mathematical understanding of the relationships between tooth working-surface deviations and the vibration excitations caused by these deviations will find the book indispensable for applications pertaining to both gear-quality and gear-health monitoring. Key features: Provides a very efficient method for measuring parallel-axis helical or spur gears in sufficient detail to enable accurate computation of transmission-error contributions from working-surface deviations, and algorithms required to carry out these computations, including examples Provides algorithms for computing the working-surface deviations causing any user-identified tone, such as ‘ghost tones,’ or ‘sidebands’ of the tooth-meshing harmonics, enabling diagnosis of their manufacturing causes, including examples Provides explanations of all harmonics observed in gear-caused vibration and noise spectra. Enables generation of three-dimensional displays and detailed numerical descriptions of all measured and computed working-surface deviations, including examples
Auf Einladung der Deutschen Forschungsgemeinschaft (DFG) fand am 9. und 10. Marz 2000 ein Rundgesprach uber heutige und kunftige Moglichkeiten des Biomonitoring in Arbeits- und Umweltmedizin statt. Das Biomonitoring hat nicht zuletzt durch die unmittelbare Umsetzung der Arbeitsergebnisse der Senatskommission zur Prufung gesundheitsschadlicher Arbeitsstoffe in geltendes Recht durch die deutsche Arbeitsschutzgesetzgebung in den letzten drei?ig Jahren in Deutschland ein hohes Niveau erreicht. Das vorliegende Buch fuhrt die Expertise verschiedener Fachdisziplinen von der Toxikologie, Arbeitsmedizin, Immunologie und Humangenetik bis hin zur Analytik und Epidemiologie zusammen. Hierbei wird die diagnostische Aussagekraft von zytogenetischen Parametern sowie von biochemischen und biologischen Effektmarkern fur die Pravention von schadstoffbedingter Erkrankungen ausfuhrlich erortert. Das gefuhrte Rundgesprach hat somit einen ersten Gedankenaustausch ermoglicht, aus dem sich kunftige Forschung entwickeln soll, um die fuhrende Rolle Deutschlands auf diesem wichtigen und sich dynamisch entwickelnden Forschungsgebiet zu halten.
There has been concerted effort across scientific disciplines to develop artificial materials and systems that can help researchers understand natural stimuli-responsive activities. With its up-to-date coverage on intelligent stimuli-responsive materials, Intelligent Stimuli-Responsive Materials provides research, industry, and academia professionals with the fundamentals and principles of intelligent stimuli-responsive materials, with a focus on methods and applications. Emphasizing nanostructures and applications for a broad range of fields, each chapter comprehensively covers a different stimuli-responsive material and discusses its developments, advances, challenges, analytical techniques, and applications.
This book provides comprehensive coverage of 3D vision systems, from vision models and state-of-the-art algorithms to their hardware architectures for implementation on DSPs, FPGA and ASIC chips, and GPUs. It aims to fill the gaps between computer vision algorithms and real-time digital circuit implementations, especially with Verilog HDL design. The organization of this book is vision and hardware module directed, based on Verilog vision modules, 3D vision modules, parallel vision architectures, and Verilog designs for the stereo matching system with various parallel architectures. Provides Verilog vision simulators, tailored to the design and testing of general vision chips Bridges the differences between C/C++ and HDL to encompass both software realization and chip implementation; includes numerous examples that realize vision algorithms and general vision processing in HDL Unique in providing an organized and complete overview of how a real-time 3D vision system-on-chip can be designed Focuses on the digital VLSI aspects and implementation of digital signal processing tasks on hardware platforms such as ASICs and FPGAs for 3D vision systems, which have not been comprehensively covered in one single book Provides a timely view of the pervasive use of vision systems and the challenges of fusing information from different vision modules Accompanying website includes software and HDL code packages to enhance further learning and develop advanced systems A solution set and lecture slides are provided on the book's companion website The book is aimed at graduate students and researchers in computer vision and embedded systems, as well as chip and FPGA designers. Senior undergraduate students specializing in VLSI design or computer vision will also find the book to be helpful in understanding advanced applications.
Provides guidance to managers, safety professionals, educators and students on having operational risk management systems that meet the requirements of Z10. Emphasizes Management Leadership and Employee Involvement, the most important section in Z10, with particular reference to contributions that employees can make. A new provision was added to Z10 on Risk Assessment which along with Avoidance of Human Error is addressed. Revised and expanded coverage of Management of Change and The Procurement Process New chapters cover Macro Thinking – The Socio-Technical Model; Safety Professionals as Culture Change Agents; Prevention through Design, and A Primer on System Safety
A comprehensive guide to the design and execution of sophisticated exterior building enclosures Focused on the design process for architects and related professionals, this book addresses the design and execution of sophisticated exterior building enclosures for a number of commercial building types and in a variety of building materials. It focuses on the design process by delineating enclosure basics, the participants (owners, architects, engineers, consultants) and their roles and responsibilities through collaboration, and tracking the design process through construction. This comprehensive handbook covers all of the factors that affect the design of a building enclosure, including function, visual aesthetics, performance requirements, and many other criteria. In-depth case studies of projects of various scales, types, and climate conditions illustrate the successful implementation of exterior wall enclosure solutions in brick masonry, stone, architectural concrete, glass, and metals. This unique and indispensable guide: Defines the functions, physical requirements, design principles, and types of exterior building enclosures Identifies the participants in the design and construction process and specifies their roles and responsibilities Presents a step-by-step process for the design of exterior enclosures, from defining goals and developing concepts through creating construction documents Reviews the construction process from bidding and negotiation through the paper phase to the «brick and mortar» stage Provides details on the properties of exterior enclosure materials, including structural considerations, weather protection, fire safety, and more Covers a variety of materials, including brick masonry, natural stone masonry, architectural concrete, metal framing and glass, and all-glass enclosures Written by the technical director of the San Francisco office of Skidmore, Owings & Merrill, Exterior Building Enclosures is an indispensable resource for architects, engineers, facade consultants, and green design consultants working on commercial building projects.