Hand cream, detergent, shower gel, toothpaste, toilet cleaner, air freshener, lipstick, perfume, low-fat spread, painkiller, diet drink, insect repellent… hundreds of everyday products that make our lives so much better than those of our forebears. And yet most of us know little about the ingredients they contain and why they deliver the benefits we enjoy. Some people find it worrying when they examine the list of ingredients on a packaging label, because all they read may be unintelligible names or E numbers. It appears to be just chemicals, chemicals, chemicals. The aim of this book is to examine the ingredients more closely and explain the reasons for their being used.Start reading and stop worrying.Chemistry at Home has been written by award-winning popular science writer and chemist, John Emsley, using non-technical language. The book has 12 chapters, each devoted to the kinds of products we are likely to find around the home, including in the garage and the garden shed. Chemistry at Home also includes a glossary which gives more technical information about the molecules mentioned in the book.
Textiles are ubiquitous materials that many of us take for granted in our everyday lives. We rely on our clothes to protect us from the environment and use them to enhance our appearance. Textiles also find applications in transport, healthcare, construction, and many other industries.<BR>The revised and updated 2nd Edition of The Chemistry of Textile Fibres highlights the trend towards the synthesis, from renewable resources, of monomers for making synthetic fibres. It contains new information on the influence of legislation and the concerns of environmental organisations on the use of chemicals in the textile industry. New sections on genetically modified cotton, anti-microbial materials and spider silk have been added as well as a new chapter covering functional fibres and fabrics.<BR>This book provides a comprehensive overview of the various types of textile fibres that are available today, ranging from natural fibres to the high-performance fibres that are very technologically advanced. Readers will gain an appreciation of why particular types of fibre are used for certain applications through understanding the chemistry behind their properties.<BR>Students following ‘A’ level courses or equivalent and first-year undergraduate students reading textile technology subjects at university will find this book a valuable source of information.<BR>
The inner architecture of a material can have an astonishing effect on its overall properties and is vital to understand when designing new materials. Nature is a master at designing hierarchical structures and so researchers are looking at biological examples for inspiration, specifically to understand how nature arranges the inner architectures for a particular function in order to apply these design principles into man-made materials. Materials Design Inspired by Nature is the first book to address the relationship between the inner architecture of natural materials and their physical properties for materials design. The book explores examples from plants, the marine world, arthropods and bacteria, where the inner architecture is exploited to obtain specific mechanical, optical or magnetic properties along with how these design principles are used in man-made products. Details of the experimental methods used to investigate hierarchical structures are also given. Written by leading experts in bio-inspired materials research, this is essential reading for anyone developing new materials.
The focus of this excellent textbook is the topic of molecular reaction dynamics. The chapters are all written by internationally recognised researchers and, from the outset, the contributors are writing with the young scientist in mind. The easy to use, stand-alone, chapters make it of value to students, teachers, and researchers alike. Subjects covered range from the more traditional topics, such as potential energy surfaces, to more advanced and rapidly developing areas, such as femtochemistry and coherent control. The coverage of reaction dynamics is very broad, so many students studying chemical physics will find elements of this text interesting and useful. Tutorials in Molecular Reaction Dynamics includes extensive references to more advanced texts and research papers, and a series of 'Study Boxes' help readers grapple with the more difficult concepts. Each chapter is thoroughly cross-referenced, helping the reader to link concepts from different branches of the subject. Worked problems are included, and each chapter concludes with a selection of problems designed to test understanding of the subjects covered. Supplementary reading material, and worked solutions to the problems, are contained on a secure website.
The use of Compound-specific Stable Isotope Analysis (CSIA) is increasing in many areas of science and technology for source allocation, authentication, and characterization of transformation reactions. Until now, there have been no textbooks available for students with an analytical chemical background or basic introductory books emphasising the instrumentation and theory. This book is the first to focus solely on stable isotope analysis of individual compounds in sometimes complex mixtures. It acts as both a lecture companion for students and a consultant for advanced scientists in fields including forensic and environmental science. The book starts with a brief history of the field before going on to explain stable isotopes from scratch. The different ways to express isotope abundances are introduced together with isotope effects and isotopic fractionation. A detailed account of the required technical equipment and general procedures for CSIA is provided. This includes sections on derivatization and the use of microextraction techniques in GC-IRMS. The very important topic of referencing and calibration in CSIA is clearly described. This differs from approaches used in quantitative analysis and is often difficult for the newcomer to comprehend. Examples of successful applications of CSIA in food authenticity, forensics, archaeology, doping control, environmental science, and extraterrestrial materials are included. Applications in isotope data treatment and presentation are also discussed and emphasis is placed on the general conclusions that can be drawn from the uses of CSIA. Further instrumental developments in the field are highlighted and selected experiments are introduced that may act as a basis for a short practical course at graduate level.
The importance of reconciling the continuing needs of humankind with the protection of the environment and the earth's ability to provide for those needs is now better recognised. Chemistry and chemical technology play an important role in this, though not on their own. Interdisciplinarity and multidisciplinarity are, therefore, critically important concepts. This book, the first of its kind, provides an interdisciplinary introduction to sustainability issues in the context of chemistry and chemical technology. The prime objective of this book is to equip young chemists (and others) to better appreciate, defend and promote the role that chemistry and its practitioners play in moving towards a society better able to control, manage and ameliorate its impact on the ecosphere. To do this, it is necessary to set the ideas, concepts, achievements and challenges of chemistry and its application in the context of its environmental impact, past, present and future, and the changes needed to bring about a more sustainable yet equitable world. Covering aspects assumed, barely addressed or neglected in previous publications – it puts Green Chemistry in a much wider (historic, scientific, technological, intellectual and societal) context and addresses complexities and challenges associated with attitudes to science and technology, media treatment of scientific and technological controversies and difficulties in reconciling environmental protection and global development. While the book stresses the central importance of rigour in the collection and treatment of evidence and reason in decision-making, to ensure that it meets the needs of a wide community of students, it is broad in scope, rather than deep. It is, therefore, appropriate to a wide audience including practising scientists and technologists.
Even in the 21st Century, the manufacture of leather retains an air of the dark arts, still somewhat shrouded in the mysteries of a millennia old, craft based industry. Despite the best efforts of a few scientists over the last century or so, much of the understanding of the principles of tanning is still based on received wisdom and experience. Leather is made from (usually) the hides and skins of animals – large animals such as cattle have hides, small animals such as sheep have skins. The skin of any animal is largely composed of the protein collagen, so it is the chemistry of this fibrous protein and the properties it confers to the skin with which the tanner is most concerned. In addition, other components of the skin impact on processing, impact on the chemistry of the material and impact on the properties of the product, leather. Therefore, it is useful to understand the relationships between skin structure at the molecular and macro levels, the changes imposed by modifying the chemistry of the material and the eventual properties of the leather. This book aims to contribute to changing the thinking in the industry, to continue building a body of scientific understanding, aimed at enhancing the sustainability of an industry which produces a unique group of materials, derived from a natural source. The Science of Leather is the only current text on tanning science, and addresses the scientific principles which underpin the processes involved in making leather. It is concerned with the chemical modification of collagen, prior to tanning and the tanning reactions in particular. The subject is covered in the following order: collagen chemistry, collagen structure, skin structure, processing to prepare for tanning, the tanning processes and processing after tanning. The aim of the book is to provide leather scientists and technologists with an understanding of how the reactions work, the nature of their outcomes and how the processes can be controlled and changed. The objective is to synthesise a scientific view of leather making and to arrive at an understanding of the nature of tanning – how the wide range of chemistries employed in the art can change the properties of collagen, making leather with different properties, especially conferring different degrees of stabilisation as measured by the hydrothermal stability. Environmental issues are not treated as a separate theme – the impact of leather making on the environment is a thread running through the text, with the assumption that better understanding of the science of leather making will lead to improved processing. The book also reflects on the ways leather technology may develop in the future based on the foundation of understanding the scientific principles which can be exploited. It also includes a subject index, references and a glossary. The book provides the reader with insights into the role science plays in leather technology and provides fundamental understanding, which should be the basis for scientific and technological research and development for the benefit of the global leather industry. The book is aimed at students, leather scientists and technologists, in both academia and industry, in leather production and in chemical supply houses.
This book is an appealing, concise, and factual account of the chemistry of the solar system. It includes basic facts about the chemical composition of the different bodies in the solar system, the major chemical processes involved in the formation of the Sun, planets, and small objects, and the chemical processes that determine their current chemical make-up. The book summarizes compositional data but focuses on the chemical processes and where relevant, it also emphasizes comparative planetology. There are numerous informative summary tables which illustrate the similarities (or differences) that help the reader to understand the processes described. Data is presented in graphical form which is useful for identifying common features of the major processes that determine the current chemical state of the planets. The book will interest general readers with a background in chemistry who will enjoy reading about the chemical diversity of the solar system's objects. It will serve as an introductory textbook for graduate classes in planetary sciences but will also be very popular with professional researchers in academia and government, college professors, and postgraduate fellows.
Concerns about environmental pollution, global climate change and hazards to human health have increased dramatically. This has led to a call for change in chemical processes including those that are part of chemical analysis. The development of analytical chemistry continues and every new discovery in chemistry, physics, molecular biology, and materials science brings new opportunities and challenges. Yet, contemporary analytical chemistry does not consume resources optimally. Indeed, the usage of toxic chemical compounds is at the highest rate ever. All this makes the emerging field of green chemistry a “hot topic” in industrial, governmental laboratories as well as in academia. This book starts by introducing the twelve principles of green chemistry. It then goes on to discuss how the principles of green chemistry can be used to assess the ‘greenness’ of analytical methodologies. The ‘green profile’ proposed by the ACS Green Chemistry Institute is also presented. A chapter on “Greening” sample preparation describes approaches to minimizing toxic solvent use, using non-toxic alternatives, and saving energy. The chapter on instrumental methods describes existing analytical approaches that are inherently green and making non-green methods greener. The final chapter on signal acquisition describes how quantitative structure-property relationship (QSPR) ideas could reduce experimental work thus making analysis greener. The book concludes with a discussion of how green chemistry is both possible and necessary. Green Analytical Chemistry is aimed at managers of analytical laboratories but will also interest teachers of analytical chemistry and green public policy makers.
Atmospheric Chemistry provides readers with a basic knowledge of the chemistry of Earth's atmosphere, and an understanding of the role that chemical transformations play in this vital part of our environment. The composition of the 'natural' atmosphere (troposphere, stratosphere and mesosphere) is described in terms of the physical and chemical cycles that govern the behaviour of the major and the many minor species present, and of the atmospheric lifetimes of those species. An extension of these ideas leads to a discussion of the impacts of Man's activities on the atmosphere, and to an understanding of some of the most important environmental issues of our time. One thread of the book explains how living organisms alter the composition and pressures in the atmosphere, modify temperatures, and change the intensity and wavelength-distribution of light arriving from the Sun. Meanwhile, the living organisms on Earth have depended on these very same environmental conditions being satisfactory for the maintenance and evolution of life. There thus appear to be two-way interactions between life and the atmosphere. Man, just one species of living organism, has developed an unfortunate ability to interfere with the feedbacks that seem to have maintained the atmosphere to be supportive of surface life for more than 3.5 billion years. This book will help chemists to understand the background to the problems that arise from such interference. The structure of the book and the development of the subject deviate somewhat from those usually encountered. Important and recurring concepts are presented in outline first, before more detailed discussions of the atmospheric behaviour of specific chemical species. Examples of such themes are the sources and sinks of trace gases, and their budgets and lifetimes. That is, the emphasis is initially on the principles of the subject, with the finer points emerging at later points in the book, sometimes in several successive chapters. In this way, some of the core material gets repeated exposure, but in new ways and in new contexts. The book is written at a level that makes it accessible to undergraduate chemists, and in a manner that should make it interesting to them. However, the material presented forms a solid base for those who are extending their studies to a higher level, and it will also provide non-specialists with the background to an understanding of Man's several and varied threats to the atmosphere. Well-informed citizens can then better assess measures proposed to prevent or alleviate the potential damage, and policy makers more realistically formulate the necessary controls on a sound scientific foundation.