Remote C-H Bond Functionalizations. Группа авторов

2.18 (a) meta‐C–H acetoxylation of benzoic acids. (b) Elaboration of Scheme 2.19 meta‐C–H olefination of benzoic acid derivatives with conf...Scheme 2.20 meta‐C–H olefination of aniline derivatives.Scheme 2.21 (a) synthesis of substrate from CO₂ for meta‐C–H activatio...Scheme 2.22 meta‐C–H olefination of tertiary anilines.Scheme 2.23 (a) meta‐C–H acetoxylation of aniline amides. (b) meta‐...Scheme 2.24 meta‐C–H acetoxylation of benzylamine derivatives. Scheme 2.25 meta‐C–H olefination of tertiary benzylamines and distal a...Scheme 2.26 meta‐C–H olefination of phenylethylamine derivatives.Scheme 2.27 Sequential remote‐selective regiodivergent C–H olefination of 2‐...Scheme 2.28 (a) Conformation promoted meta‐selective activation. (b) meta‐...Scheme 2.29 (a) meta‐C–H olefination of indoline derivatives. (b) Remo...Scheme 2.30 meta‐C–H arylation of indoline derivatives.Scheme 2.31 meta‐C–H acetoxylation of indoline derivatives.Scheme 2.32 meta‐C–H olefination of N‐heterocycles.Scheme 2.33 meta‐C–H olefination of 3‐phenylpyridines.Scheme 2.34 meta‐C–H olefination of 3‐phenylpyridines using nitrile‐ba...Scheme 2.35 (a) meta‐C–H olefination of benzylsulfonic acid derivative...Scheme 2.36 (a) meta‐C–H olefination of 2‐phenethylsulfonic acid deriv...Scheme 2.37 meta‐C–H olefination and alkylation of benzylsulfonyl and ...Scheme 2.38 meta‐C–H olefination and acetoxylation of benzylsulfonyl e...Scheme 2.39 Rh‐catalyzed meta‐C–H olefination of benzylsulfonyl esters...Scheme 2.40 meta‐C–H perfluoroalkenylation of benzylsulfonyl esters....Scheme 2.41 meta‐C–H allylation of benzylsulfonyl esters.Scheme 2.42 meta‐C–H oxygenation of benzylsulfonyl esters.Scheme 2.43 meta‐C–H cyanation of benzylsulfonyl and 2‐phenethylsulfon...Scheme 2.44 meta‐C–H deuteration of benzylsulfonyl esters.Scheme 2.45 meta‐C–H silylation and germanylation.Scheme 2.46 meta‐C–H olefination of phenol derivatives.Scheme 2.47 Organosilicon template assisted meta‐C–H olefination of ph...Scheme 2.48 Rh(III)‐catalyzed meta‐C–H olefination of phenol derivativ...Scheme 2.49 (a) meta‐selective C–H olefination of phenols. (b) Nickel‐cataly...Scheme 2.50 meta‐C–H olefination of 2‐phenyl phenol derivatives.Scheme 2.51 meta‐C–H olefination of benzyl alcohols. Scheme 2.52 meta‐C–H olefination of benzyl and phenyl ethyl alcohols.Scheme 2.53 meta‐C–H iodination of benzyl and phenylethyl alcohols.Scheme 2.54 meta‐C–H olefination of distal arene‐tethered alcohols.Scheme 2.55 meta‐C–H functionalizations of arenes with different linker leng...Scheme 2.56 Removal of the pyrimidine‐based template.Scheme 2.57 meta‐C–H allylation of alcohol derivatives.Scheme 2.58 meta‐C–H olefination of arene‐tethered diols.Scheme 2.59 meta‐C–H deuteration of alcohols.Scheme 2.60 meta‐C–H olefination of benzyl silanes.Scheme 2.61 (a) meta‐C–H cyanation of benzyl silanes. (b) Application of met...Scheme 2.62 meta‐C–H functionalizations of phosphonates.Scheme 2.63 meta‐C–H alkylation of phosphonates.Scheme 2.64 meta‐C–H deuteration of phosphonates.Scheme 2.65 Proposed catalytic cycle for meta‐C–H olefination.Scheme 2.66 Proposed transition state through computational study.

      2 Chapter 3Scheme 3.1 Catellani's initial report on C–H functionalization of iodoarenes...Scheme 3.2 Proposed catalytic cycle for the ortho‐C–H alkylation of aryl iod...Scheme 3.3 ortho‐C–H alkylation of ortho‐substituted iodoarenes under Pd/NBE...Scheme 3.4 Lautens' modified reaction conditions for ortho‐C–H alkylation of...Scheme 3.5 Pd(II)‐initiated C–H functionalization of arenes under Pd/NBE cat...Scheme 3.6 ortho‐Alkylation of ortho‐unsubstituted iodoarenes with two diffe...Scheme 3.7 ortho‐C–H trifluoroethylation iodoarenes with trifluoroethyl iodi...Scheme 3.8 ortho‐Alkylation with racemic secondary alkyl iodides.Scheme 3.9 ortho‐Alkylation with enantioenriched secondary alkyl iodides.Scheme