While this important reaction class is among the most important and most widely used in organic chemistry, this is the first book to summarize the many different olefination methods, including: * Wittig reaction * Peterson reaction * Julia olefination * Utilizing the Tebbe and related reagents * Low-valent chromium, zinc or titanium mediated olefination * McMurry coupling plus the related reactions in each case and the application to asymmetric synthesis. It thus collates in one ready reference the current level of knowledge as well as new developments in this constantly evolving field – information which until now has been dispersed throughout the literature.
At the very latest, with the award of the 2001 Nobel Prize for work on asymmetric oxidation, there has been a need for a comprehensive book on such methods. Edited by J.-E. Backvall, one of the world's leaders in the field, this book fills that gap by covering the topic, from classical to green chemistry methods. He has put together a plethora of well-established authors from all over the world who cover every important aspect in high-quality contributions – whether aerobic oxidation or transition metal-catalyzed epoxidation of alkenes. By providing an overview of this huge topic, this book represents an unparalleled aid for any chemist working in the field. Chapters include: Recent Developments in the Osmium-Catalyzed Dihydroxylation of Olefins Transition Metal-Catalyzed Epoxidation of Alkenes Organocatalytic Oxidation – Ketone-Catalyzed Asymmetric Epoxidation of Olefins Modern Oxidation of Alcohols using environmentally Benign Oxidants Aerobic Oxidations and Related Reactions Catalyzed by N-Hydroxyphthalimide Ruthenium-Catalyzed Oxidation of Alkenes, Alcohols, Amines, Amides, b-Lactams, Phenols, and Hydrocarbons Selective Oxidations of Sulfides and Amines Liquid Phase Oxidation Reactions Catalyzed by Polyoxometalates Oxidation of Carbonyl Compounds Mn-catalysed Oxidation with Hydrogen Peroxide
Here, the editors Rolf Gleiter and Henning Hopf present an excellent overview of all the important aspects and latest results in cyclophane chemistry. Clearly structured and covering the entire range, the book introduces readers to the most recent research in the field. Twenty chapters, written by well-known scientists, cover in particular: – synthesis of carbo- and heterocyclic cyclophanes and metallocenophanes, – structural and spectroscopic properties of cyclophanes, – current and future applications in synthesis and material science, – novel reactions of cyclophanes, – use of cyclophanes as building blocks in supramolecular chemistry for this fascinating class of compounds. Thus, this is not only an extremely valuable source of information for synthetic organic chemists, but also a ready reference for scientists working in related fields of arene chemistry, stereoselective synthesis, material science, and bioorganic chemistry.
Organonickel chemistry plays an increasingly important role in organic chemistry, and interest in this topic is now just as keen as in organopalladium chemistry. While there are numerous, very successful books on the latter, a book specializing in organonickel chemistry is long overdue. Edited by one of the leading experts in the field, this volume covers the many discoveries made over the past 30 years, and previously scattered throughout the literature. Active researchers working at the forefront of organonickel chemistry provide a comprehensive review of the topic, including cross-coupling reactions, asymmetric synthesis and heterogeneous catalysis reaction types. A must-have for both organometallic chemists and synthetic organic chemists.
In this handbook, Peer Kirsch clearly shows that this exciting field is no longer an exotic area of research. Aimed primarily at synthetic chemists wanting to gain a deeper understanding of the fascinating implications of including the highly unusual element fluorine in organic compounds, the main part of the book presents a wide range of synthetic methodologies and the experimental procedures selected undeniably show that this can be done with standard laboratory equipment. To round off, the author looks at fluorous chemistry and the applications of organofluorine compounds in liquid crystals, polymers and more besides. This long-awaited book represents an indispensable source of high quality information for everyone working in the field.
Nitric oxide is a highly potent regulatory molecule with great pharmaceutical potential. This handbook fills a real gap in combining the chemistry of nitric oxide releasing substances with their practical applications in biology and drug design. It covers all classes of nitric oxide donors, from organic nitrates to nitroso compounds, guanidines and metal-NO complexes. In addition to a detailed treatment of the chemistry of NO donors, numerous examples of successful diagnostic and pharmacological applications are discussed, as well as further therapeutic targets for these substances.
This textbook is aimed at the majority of students, who need to quickly acquire a concise overview of soil science. Many current soil science textbooks still cater for a traditional student market where students embark on three years study in a narrow discipline. The growth in modular degree schemes has meant that soil science is now often taught as self-standing unit as part of broad based degree program. Students pursuing this type of course are increasingly reluctant to purchase expensive textbooks that are too detailed and often assume a scientific background. For those opting to specialise in soil science there are a variety of good textbooks to choose from. This short informative guide, will be particularly useful for students who do not possess a traditional scientific background, such as those studying geography, environment science, ecology and agriculture. Only textbook to cater for introductory courses in soil science. Provides an affordable concise overview of soil science. Learning exercises and chapter summaries enhance usability. Annotated suggestions for further reading. Based on proven and successful modular course structure. Emphasis on readability and interactive learning. No scientific background assumed.
Reap the benefits of sludge The processing of wastewater sludge for use or disposal has been a continuing challenge for municipal agencies. Yet, whensludge is properly processed, the resulting nutrient-rich product–biosolids–can be a valuable resource for agriculture and other uses. Wastewater Sludge Processing brings together a wide body of knowledge from the field to examine how to effectively process sludge to reap its benefits, yet protect public health. Presented in a format useful as both a reference for practicing environmental engineers and a textbook for graduatestudents, this book discusses unit operations used for processing sludge and the available methods for final disposition of the processed product. Topics discussed include sludge quantities and characteristics, thickening and dewatering, aerobicand anaerobic digestion, alkaline stabilization, composting, thermal drying and incineration, energy consumption, and the beneficial use of biosolids. COMPREHENSIVE IN ITS COVERAGE, THE TEXT: * Describes new and emerging technologies as well as international methods * Compares different types of sludge processing methods * Explains both municipal and industrial treatment technologies Written by authors with decades of experience in the field, Wastewater Sludge Processing is an invaluable tool for anyone planning, designing, and implementing municipal wastewater sludge management projects.
Written by internationally recognised leaders in the field, Metal Amide Chemistry is the authoritative survey of this important class of compounds, the first since Lappert and Power’s 1980 book “Metal and Metalloid Amides.” An introduction to the topic is followed by in-depth discussions of the amide compounds of: alkali metals alkaline earth metals zinc, cadmium and mercury the transition metals group 3 and lanthanide metals group 13 metals silicon and the group 14 metals group 15 metals the actinide metals Accompanied by a substantial bibliography, this is an essential guide for researchers and advanced students in academia and research working in synthetic organometallic, organic and inorganic chemistry, materials chemistry and catalysis.
Persistent Organic Pollutants (POPs) are toxic, resistant to degradation, bioaccumulative, and display wide spatial distribution. They accumulate in humans and wildlife, and have been linked to cancer, as well as reproductive and immunological disorders. In 2001 a global treaty on POPs was agreed, to minimise and ultimately eliminate the release of POPs into the environment. The Stockholm Convention lists 12 groups of chemicals, and as of late 2008, a further 12 chemicals are under consideration for inclusion. This book addresses all of these chemicals, but focuses particularly on currently listed POPs that are still of major concern (e.g. polychlorinated biphenyls – PCBs), as well as new and emerging POPs that have been the subject of an explosion of scientific interest in the last decade, i.e. brominated flame retardants (BFRs) and perfluorinated chemicals (PFCs). Other chapters address the challenges posed by the presence of POPs in the developing world; how the properties of chiral POPs can provide unique insights into their environmental sources, fate and behaviour; and issues arising from the presence of POPs in urban and indoor environments. Persistent Organic Pollutants provides a much-anticipated reference source for a wide audience including academics, industrial scientists and regulators.