Mathematics for Enzyme Reaction Kinetics and Reactor Performance. F. Xavier Malcata

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Название Mathematics for Enzyme Reaction Kinetics and Reactor Performance
Автор произведения F. Xavier Malcata
Жанр Химия
Серия
Издательство Химия
Год выпуска 0
isbn 9781119490333



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      Therefore, multiplication of scalar by matrix is distributive, with regard to addition of matrices.

      (4.35)equation

      as per Eq. (4.9) – which becomes

      (4.36)equation

      owing to Eq. (4.20), coupled with the distributive property of multiplication of plain scalars. Reverse application of Eq. (4.4) leads to

      (4.37)equation

      and an extra utilization of Eq. (4.20) entails

      (4.38)equation

      – or else

      A final property pertains to product of (scalar) unity by a matrix, according to

      (4.40)equation

      based on Eq. (4.2); application of Eq. (4.20) permits, in turn, transformation to

      (4.42)equation

      that is equivalent to

      (4.43)equation

      in view again of Eq. (4.2) – thus leaving the matrix unchanged, whatever it is; 1 is accordingly confirmed as the neutral element of multiplication of scalar by matrix.

      When the scalar at stake is 1, its product by matrix A transforms every element thereof to its negative; the result, usually denoted as −A, looks like

      as per Eqs. (4.2) and (4.20). Matrix −A is called symmetric of A – because addition of those two matrices produces a nil matrix, i.e.

      If (m × n) matrix A, or [ai,j] as per Eq. (4.2), and (n × p) matrix B, defined as

      are considered – with number of columns of A equal to number of rows of B, then the said matrices can be multiplied via

      the product is an (m × p) matrix, with generic element di,l .

      Note that multiplication in reverse order will not be possible unless p = m, due to the matching between number of columns of B and number of rows of A that would then be required; this example suffices to prove that multiplication of matrices is not commutative. However, even in the case of (n × n) matrices A and B that can be multiplied in either order, one gets

      (4.48)equation

      (4.49)equation

      with generic element ek,j – written with the aid of the commutative property of multiplication of scalars. The equality of di,l to ej,k cannot be guaranteed, because the elements chosen for the partial two‐factor products are not the same; for instance, the element positioned in the first row and column of AB looks like images, whereas the corresponding element of BA reads images – which is obviously distinct from the former, despite coincidence of (only) the first term.