Mathematics for Enzyme Reaction Kinetics and Reactor Performance. F. Xavier Malcata

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Название Mathematics for Enzyme Reaction Kinetics and Reactor Performance
Автор произведения F. Xavier Malcata
Жанр Химия
Серия
Издательство Химия
Год выпуска 0
isbn 9781119490333



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      In the particular case Pm is a linear polynomial, of the form xr, viz.

      en lieu of Eq. (2.136) and meaning that b0 = −r and b1 = 1, the algorithm of division of polynomials simplifies to

      (2.147)equation

      which breaks down to

      (2.148)equation

      upon condensation of terms alike; a second application of said algorithm unfolds

      (2.149)equation

      (2.150)equation

      This process may then be iterated until the numerator of the last term reduces to a constant – according to

      (2.151)equation

      – or, after having eliminated inner parentheses,

Image described by caption.

      (2.153)equation

      when

      (2.155)equation

      Eq. (2.155) may be rephrased as

      (2.156)equation

      or, in view of Eq. (2.135),

      (2.157)equation

      Therefore, the linear polynomial xr divides Pn {x} exactly – or Pn {x} is a multiple of xr, when x = r is a root of Pn {x}.

      2.2.3 Factorization

      (2.158)equation

      Eq. (2.159) indicates that xr will be a factor of polynomial Pn whenever r is itself a root of Pn . This very same conclusion may be achieved after recalling that a function, f {x}, may in general be represented by an infinite series on x, i.e.

      according to Taylor’s theorem (to be derived in due course) – where ξ denotes any point of the interval of definition of f {x}; in the particular case of an nth‐degree polynomial, the said expansion becomes finite and entails only n + 1 terms, according to

      with the aid of Eq. (2.135), for the simple reason that dn+1 Pn /dxn+1 = dn+2 Pn /dxn+2 == 0. Under such circumstances, Taylor’s coefficients look like

      (2.162)equation

      where a1, a2, …, an−1