Extrinsic and Intrinsic Approaches to Self-Healing Polymers and Polymer Composites. Ming Qiu Zhang

      

      Table of Contents

      1  Cover

      2  Title Page

      3  Copyright Page

      4  Preface

      5  1 Basics of Self‐Healing – State of the Art 1.1 Background 1.2 Intrinsic Self‐Healing 1.3 Extrinsic Self‐Healing 1.4 Insights for Future Work References

      6  2 Extrinsic Self‐Healing via Addition Polymerization 2.1 Design and Selection of Healing System 2.2 Microencapsulation of Mercaptan and Epoxy by In‐Situ Polymerization 2.3 Filling Polymeric Tubes with Mercaptan and Epoxy 2.4 Characterization of Self‐Healing Functionality 2.5 Concluding Remarks References

      7  3 Extrinsic Self‐Healing Via Cationic Polymerization 3.1 Thermosetting 3.2 Thermoplastics 3.3 Concluding Remarks References

      8  4 Extrinsic Self‐Healing via Anionic Polymerization 4.1 Preparation of Epoxy‐Loaded Microcapsules and Latent Hardener 4.2 Self‐Healing Epoxy Materials with Embedded Epoxy‐Loaded Microcapsules and Latent Hardener 4.3 Self‐Healing Epoxy/Woven Glass Fabric Composites with Embedded Epoxy‐Loaded Microcapsules and Latent Hardener – Healing of Interlaminar Failure 4.4 Durability of Healing Ability 4.5 Self‐Healing Epoxy/Woven Glass Fabric Composites with Embedded Epoxy‐Loaded Microcapsules and Latent Hardener – Healing of Impact Damage 4.6 Concluding Remarks References

      9  5 Extrinsic Self‐Healing Via Miscellaneous Reactions 5.1 Extrinsic Self‐Healing Via Nucleophilic Addition and Ring‐Opening Reactions 5.2 Extrinsic Self‐Healing Via Living Polymerization 5.3 Extrinsic Self‐Healing Via Free Radical Polymerization 5.4 Concluding Remarks References

      10  6 Intrinsic Self‐Healing Via the Diels–Alder Reaction 6.1 Molecular Design and Synthesis 6.2 Blends of DGFA and FGE 6.3 Concluding Remarks References

      11  7 Intrinsic Self‐Healing Via Synchronous Fission/Radical Recombinationof the C─ON Bond 7.1 Thermal Reversibility of Alkoxyamine in Polymer Solids 7.2 Self‐Healing Cross‐linked Polystyrene 7.3 Self‐Healing Epoxy 7.4 Self‐Healing Polymers Containing Alkoxyamine with Oxygen Insensitivity and Reduced Homolysis Temperature 7.5 Reversible Shape Memory Polyurethane Network with Intrinsic Self‐Healability of Wider Crack 7.6 Concluding Remarks References

      12  8 Intrinsic Self‐Healing Via Exchange Reaction of the Disulfide Bond 8.1 Room‐Temperature Self‐Healable and Remoldable Cross‐Linked Polysulfide 8.2 Sunlight Driven Self‐Healing Cross‐Linked Polyurethane Containing the Disulfide Bond 8.3 Self‐Healing and Reclaiming of Vulcanized Rubber 8.4 Concluding Remarks References

      13  Index

      14  End User License Agreement

      List of Tables

      1 Chapter 1Table 1.1 Typical intrinsic self‐healing polymers toward mechanical propert...Table 1.2 Typical intrinsic self‐healing polymers toward mechanical propert...

      2 Chapter 2Table 2.1 Descriptions of the PMF‐walled microcapsules containing mercaptan...Table 2.2 Typical PMF‐walled microcapsules containing epoxy (DTP) prepared ...Table 2.3 Properties of epoxy resins.Table 2.4 Properties of mercaptan.Table 2.5 Description of the epoxy‐loaded microcapsules