Homogeneous catalysis made easy through real-world examples and illustrations. The field of homogeneous catalysis has grown dramatically over the past decade, boasting many new applications in the chemical, fine chemical, and pharmaceutical industries. This timely work offers a unified, easy-to-understand treatment of this challenging area of chemistry. With a practical emphasis and a thorough, selective survey of current literature, the authors present homogeneous catalytic reactions proven successful in industrial applications-illustrating both the mechanistic principles and illuminating new areas of academic and industrial research. An ideal self-study guide for inorganic chemists seeking to gain entry into the field as well as a much-needed reference for industry professionals, Homogeneous Catalysis: Mechanisms and Industrial Applications features: * Clear discussions of the fundamental chemical and chemical engineering concepts relevant to homogeneous catalysis * Important examples from selected industrial processes * Extensive references to cutting-edge research with application potential (through March of 1999) * Many tables and more than 100 illustrations to help explain difficult concepts * Problems of variable complexities accompanying each chapter
Over the last decade, the area of homogeneous catalysis with transition metal has grown in great scientific interest and technological promise, with research in this area earning three Nobel Prizes and filing thousands of patents relating to metallocene and non-metallocene single site catalysts, asymmetric catalysis, carbon-carbon bond forming metathesis and cross coupling reactions. This text explains these new developments in a unified, cogent, and comprehensible manner while also detailing earlier discoveries and the fundamentals of homogeneous catalysis. Serving as a self-study guide for students and all chemists seeking to gain entry into this field, it can also be used by experienced researchers from both academia and industry for referring to leading state of the art review articles and patents, and also as a quick self-study manual in an area that is outside their immediate expertise. The book features: • Topics including renewable feed stocks (biofuel, glycerol), carbon dioxide based processes (polycarbonates), fluorous solvents, ionic liquid, hydroformylation, polymerization, oxidation, asymmetric catalysis, and more • Basic principles of organometallic chemistry, homogeneous catalysis, and relevant technological issues • Problems and answers, industrial applications (case studies), and examples from proven industrial processes with clear discussions on environmental and techno-commercial issues • Extensive references to cutting edge research with application potential and leading patents • Tables and illustrations to help explain difficult concepts