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Over the last decade, the area of homogeneous catalysis with transition metal has grown in great scientific interest and technological promise, with research in this area earning three Nobel Prizes and filing thousands of patents relating to metallocene and non-metallocene single site catalysts, asymmetric catalysis, carbon-carbon bond forming metathesis and cross coupling reactions. This text explains these new developments in a unified, cogent, and comprehensible manner while also detailing earlier discoveries and the fundamentals of homogeneous catalysis. Serving as a self-study guide for students and all chemists seeking to gain entry into this field, it can also be used by experienced researchers from both academia and industry for referring to leading state of the art review articles and patents, and also as a quick self-study manual in an area that is outside their immediate expertise. The book features: • Topics including renewable feed stocks (biofuel, glycerol), carbon dioxide based processes (polycarbonates), fluorous solvents, ionic liquid, hydroformylation, polymerization, oxidation, asymmetric catalysis, and more • Basic principles of organometallic chemistry, homogeneous catalysis, and relevant technological issues • Problems and answers, industrial applications (case studies), and examples from proven industrial processes with clear discussions on environmental and techno-commercial issues • Extensive references to cutting edge research with application potential and leading patents • Tables and illustrations to help explain difficult concepts
Micromechanics of Fracture and Damage
This book deals with the mechanics and physics of fractures at various scales. Based on advanced continuum mechanics of heterogeneous media, it develops a rigorous mathematical framework for single macrocrack problems as well as for the effective properties of microcracked materials. In both cases, two geometrical models of cracks are examined and discussed: the idealized representation of the crack as two parallel faces (the Griffith crack model), and the representation of a crack as a flat elliptic or ellipsoidal cavity (the Eshelby inhomogeneity problem). The book is composed of two parts: – The first part deals with solutions to 2D and 3D problems involving a single crack in linear elasticity. Elementary solutions of cracks problems in the different modes are fully worked. Various mathematical techniques are presented, including Neuber-Papkovitch displacement potentials, complex analysis with conformal mapping and Eshelby-based solutions. – The second part is devoted to continuum micromechanics approaches of microcracked materials in relation to methods and results presented in the first part. Various estimates and bounds of the effective elastic properties are presented. They are considered for the formulation and application of continuum micromechanics-based damage models.
Responsive Polymer Surfaces. Dynamics in Surface Topography
Adopting an integrated approach, this book covers experiments, theory, and emerging applications. In the first part surfaces are described that change from flat to either a random corrugated or to a well-structured structure, while the second part deals with those surface structures integrated in the coating surface where the structures change their shape or dimension when addressed by an external trigger. A variety of materials are addressed, including liquid crystal polymers, hydrogels, hard acrylates, and soft silicones. The whole is rounded off by a discussion of various applications, including surface controlled flows in microfluidic systems. Of interest to chemists and engineers, researchers in industry and academia, as well as those working in the paint industry and hydrodynamics.
Food Allergen Testing. Molecular, Immunochemical and Chromatographic Techniques
An in-depth review of the current scientific knowledge on food allergens testing, covering the major methodologies and techniques used to detect food allergens. Food allergens are a series of agents, mainly proteins, which cause various unpleasant and sometimes clinical symptoms in humans through consumption of foods. Perhaps surprisingly, there are no treatments against food allergies which have been found to be 100% effective. The scope for individual difference in terms of how a person reacts to a given allergen is massive, making it incredibly difficult and complex to try and medicate against allergies. Food Allergens Testing takes a thorough look at modern molecular biology and immunochemical techniques used to detect food allergens. The eleven chapters constitute an in-depth review of the current scientific knowledge on food allergens, covering the major methodologies and techniques used in validated analytical approaches. The book is aimed at scientists and technical staff in the food industry and analytical laboratories who need an up-to-date treatment of both fundamental and applied research goals on food allergens, as well as a report on the validated methods currently in use for food allergens testing.
Delayed and Network Queues
Presents an introduction to differential equations, probability, and stochastic processes with real-world applications of queues with delay and delayed network queues Featuring recent advances in queueing theory and modeling, Delayed and Network Queues provides the most up-to-date theories in queueing model applications. Balancing both theoretical and practical applications of queueing theory, the book introduces queueing network models as tools to assist in the answering of questions on cost and performance that arise throughout the life of a computer system and signal processing. Written by well-known researchers in the field, the book presents key information for understanding the essential aspects of queues with delay and networks of queues with unreliable nodes and vacationing servers. Beginning with simple analytical fundamentals, the book contains a selection of realistic and advanced queueing models that address current deficiencies. In addition, the book presents the treatment of queues with delay and networks of queues, including possible breakdowns and disruptions that may cause delay. Delayed and Network Queues also features: Numerous examples and exercises with applications in various fields of study such as mathematical sciences, biomathematics, engineering, physics, business, health industry, and economics A wide array of practical applications of network queues and queueing systems, all of which are related to the appropriate stochastic processes Up-to-date topical coverage such as single- and multiserver queues with and without delays, along with the necessary fundamental coverage of probability and difference equations Discussions on queueing models such as single- and multiserver Markovian queues with balking, reneging, delay, feedback, splitting, and blocking, as well as their role in the treatment of networks of queues with and without delay and network reliability Delayed and Network Queues is an excellent textbook for upper-undergraduate and graduate-level courses in applied mathematics, queueing theory, queueing systems, probability, and stochastic processes. The book is also an ideal reference for academics and practitioners in mathematical sciences, biomathematics, operations research, management, engineering, physics, business, economics, health industry, and industrial engineering. Aliakbar Montazer Haghighi, PhD, is Professor and Head of the Department of Mathematics at Prairie View A&M University, USA, as well as founding Editor-in-Chief of Applications and Applied Mathematics: An International Journal (AAM). His research interests include probability, statistics, stochastic processes, and queueing theory. Among his research publications and books, Dr. Haghighi is the coauthor of Difference and Differential Equations with Applications in Queueing Theory (Wiley, 2013). Dimitar P. Mishev, PhD, is Professor in the Department of Mathematics at Prairie View A&M University, USA. His research interests include differential and difference equations and queueing theory. The author of numerous research papers and three books, Dr. Mishev is the coauthor of Difference and Differential Equations with Applications in Queueing Theory (Wiley, 2013).
Ecological Biochemistry. Environmental and Interspecies Interactions
The first stand-alone textbook for at least ten years on this increasingly hot topic in times of global climate change and sustainability in ecosystems. Ecological biochemistry refers to the interaction of organisms with their abiotic environment and other organisms by chemical means. Biotic and abiotic factors determine the biochemical flexibility of organisms, which otherwise easily adapt to environmental changes by altering their metabolism. Sessile plants, in particular, have evolved intricate biochemical response mechanisms to fit into a changing environment. This book covers the chemistry behind these interactions, bottom up from the atomic to the system's level. An introductory part explains the physico-chemical basis and biochemical roots of living cells, leading to secondary metabolites as crucial bridges between organisms and the respective ecosystem. The focus then shifts to the biochemical interactions of plants, fungi and bacteria within terrestrial and aquatic ecosystems with the aim of linking biochemical insights to ecological research, also in human-influenced habitats. A section is devoted to methodology, which allows network-based analyses of molecular processes underlying systems phenomena. A companion website offering an extended version of the introductory chapter on Basic Biochemical Roots is available at http://www.wiley.com/go/Krauss/Nies/EcologicalBiochemistry
Mathematische Statistik. Für Mathematiker, Natur- und Ingenieurwissenschaftler
"Mathematische Statistik" hat wegen des gro?en Anwendungsbedarfes stetig an Attraktivitat gewonnen – und auch theoretisch sind neue Ansatze entwickelt worden. Ein besonderer Schwerpunkt liegt auf der Versuchsplanung, die haufig gegenuber der Auswertung vernachlassigt wird. Unter konsequenter Berucksichtigung der Entwicklungen der letzten Jahrzehnte ist ein neues Buch entstanden. Kenntnisse in der Ma?theorie und der Wahrscheinlichkeitsrechnung sind hilfreich, aber nicht notwendig, da die Autoren die Materie leicht verstandlich beschrieben haben. Ein Schwerpunkt liegt auf der Versuchsplanung, die zu oft vernachlassigt wird und oft neben der Auswertung benachteiligt ist. Konsequenterweise nimmt in diesem Buch die Planung des Stichprobenumfangs und die Beschreibung von Versuchsanlagen einen gro?en Raum ein – immer eingebettet in die passenden Auswertungsverfahren wie die Varianz- und Regressionsanalyse. Ein Muss fur alle Natur- und Ingenieurwissenschaftler, die empirisch arbeiten und daneben auch an der Begrundung der Methoden interessiert sind.
Digital Communications 2. Digital Modulations
This second volume covers the following blocks in the chain of communication: the modulation baseband and transposed band, synchronization and channel estimation as well as detection. Variants of these blocks, the multicarrier modulation and coded modulations are used in current systems or future.
Ethnobotany. A Phytochemical Perspective
Ethnobotany: A Phytochemical Perspective explores the chemistry behind hundreds of plant medicines, dyes, fibers, flavors, poisons, insect repellants, and many other uses of botanicals. Bridging the gap between ethnobotany and chemistry, this book presents an introduction to botany, ethnobotany, and phytochemistry to clearly join these fields of study and highlight their importance in the discovery of botanical uses in modern industry and research. Part I. Ethnobotany, explores the history of plant exploration, current issues such as conservation and intellectual property rights, and a review of plant anatomy. An extensive section on plant taxonomy highlights particularly influential and economically important plants from across the plant kingdom. Part II. Phytochemistry, provides fundamentals of secondary metabolism, includes line drawings of biosynthetic pathways and chemical structures, and describes traditional and modern methods of plant extraction and analysis. The last section is devoted to the history of native plants and people and case studies on plants that changed the course of human history from five geographical regions: Africa, the Americas, Asia, Europe, and Ocean. Throughout the entire book, vivid color photographs bring science to life, capturing the essence of human botanical knowledge and the beauty of the plant kingdom.
Hydrogen Production. by Electrolysis
Covering the various aspects of this fast-evolving field, this comprehensive book includes the fundamentals and a comparison of current applications, while focusing on the latest, novel achievements and future directions. The introductory chapters explore the thermodynamic and electrochemical processes to better understand how electrolysis cells work, and how these can be combined to build large electrolysis modules. The book then goes on to discuss the electrolysis process and the characteristics, advantages, drawbacks, and challenges of the main existing electrolysis technologies. Current manufacturers and the main features of commercially available electrolyzers are extensively reviewed. The final chapters then present the possible configurations for integrating water electrolysis units with renewable energy sources in both autonomous and grid-connected systems, and comment on some relevant demonstration projects. Written by an internationally renowned team from academia and industry, the result is an invaluable review of the field and a discussion of known limitations and future perspectives.